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Issue 8, 2015
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Synthesis, structural characterization and thermal properties of copper and silver silyl complexes

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Abstract

The synthesis of copper and silver silyl complexes containing either N-heterocyclic carbenes or nitrogen donors is described. Alterations made to both the neutral donor ligands as well as the silyl group provided access to a number of different compounds. Many of the complexes synthesized were studied in the solid state and the effect of the donor ligand on the final structure of the complexes was examined. The thermal properties of the complexes were explored using thermogravimetric analysis, differential scanning calorimetry and sublimations. Some of the complexes synthesized were demonstrated to be promising volatile metal precursors.

Graphical abstract: Synthesis, structural characterization and thermal properties of copper and silver silyl complexes

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The article was received on 09 Dec 2014, accepted on 07 Jan 2015 and first published on 12 Jan 2015


Article type: Paper
DOI: 10.1039/C4DT03770G
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Dalton Trans., 2015,44, 3817-3828

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    Synthesis, structural characterization and thermal properties of copper and silver silyl complexes

    M. J. Sgro, W. E. Piers and P. E. Romero, Dalton Trans., 2015, 44, 3817
    DOI: 10.1039/C4DT03770G

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