Issue 40, 2015
From the journal:

CrystEngComm

Coexistence of a pair of enantiomorphic forms of chiral quartz nets with an interpenetrating mode in a centrosymmetric coordination polymer†

Yu-Ling Wang,a   Lin Chen,a   Qing-Yan Liu,*a   Zi-Yi Dub  and  Yang Yaoa  

* Corresponding authors

a Key Laboratory of Small Functional Organic Molecule of Ministry of Education, College of Chemistry Chemical Engineering, Jiangxi Normal University, Nanchang 330022, Jiangxi, PR China
E-mail: qyliuchem@hotmail.com

b College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, PR China

Abstract

2-Fold interpenetrating chiral quartz nets with opposite handedness have been observed in a centrosymmetric coordination polymer {[Zn3(bmzbc)6]·11.5DMF}n (Hbmzbc = 4-(benzimidazole-1-yl)benzoic acid), which is a unique example of an interpenetrating enantiomorphic pair of quartz nets that have never been realized before.

Graphical abstract: Coexistence of a pair of enantiomorphic forms of chiral quartz nets with an interpenetrating mode in a centrosymmetric coordination polymer

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Article information

DOI
https://doi.org/10.1039/C5CE01400J
Article type
Communication
Submitted
16 Jul 2015
Accepted
07 Sep 2015
First published
08 Sep 2015

CrystEngComm, 2015,17, 7628-7631

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Coexistence of a pair of enantiomorphic forms of chiral quartz nets with an interpenetrating mode in a centrosymmetric coordination polymer

Y. Wang, L. Chen, Q. Liu, Z. Du and Y. Yao, CrystEngComm, 2015, 17, 7628 DOI: 10.1039/C5CE01400J

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