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Issue 40, 2015
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Crystal-to-crystal transformation of fishnet-like layered compounds: a self-locking structure with position-variable intercalated molecules

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Abstract

Fishnet-like layered compounds comprising trifluoroacetate-bridged paddlewheel dimetal(II, II) complexes and 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) were crystalized with anthracene (ANT) molecules between their layers and crystallization solvents at their hexagonal columnar pores. These complexes undergo a solvent-release crystal-to-crystal transformation involving the migration of a portion of the ANT molecules from between the layers to the hexagonal pores, effectively locking the slidable layers.

Graphical abstract: Crystal-to-crystal transformation of fishnet-like layered compounds: a self-locking structure with position-variable intercalated molecules

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Publication details

The article was received on 30 Jun 2015, accepted on 24 Jul 2015 and first published on 24 Jul 2015


Article type: Communication
DOI: 10.1039/C5CE01260K
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CrystEngComm, 2015,17, 7618-7622

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    Crystal-to-crystal transformation of fishnet-like layered compounds: a self-locking structure with position-variable intercalated molecules

    M. Nishio, N. Motokawa and H. Miyasaka, CrystEngComm, 2015, 17, 7618
    DOI: 10.1039/C5CE01260K

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