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Issue 46, 2015
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Solvent-induced single-crystal to single-crystal transformation of a Zn4O-containing doubly interpenetrated metal–organic framework with a pcu net

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Abstract

Guest molecules in a metal–organic framework (MOF), [Zn4O(CPMA)3]·6DMF (DMF = N,N-dimethylformamide), with an interpenetrating pcu net were exchanged with benzene, n-hexane, and methanol in a single-crystal to single-crystal (SC–SC) manner, which involved the sliding motion of the interpenetrating network, as well as the dynamic movements of the molecular components, and was triggered by host–guest interactions.

Graphical abstract: Solvent-induced single-crystal to single-crystal transformation of a Zn4O-containing doubly interpenetrated metal–organic framework with a pcu net

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Supplementary files

Article information


Submitted
03 Jun 2015
Accepted
30 Jul 2015
First published
30 Jul 2015

CrystEngComm, 2015,17, 8807-8811
Article type
Communication
Author version available

Solvent-induced single-crystal to single-crystal transformation of a Zn4O-containing doubly interpenetrated metal–organic framework with a pcu net

J. H. Lee, T. K. Kim, M. P. Suh and H. R. Moon, CrystEngComm, 2015, 17, 8807
DOI: 10.1039/C5CE01074H

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