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Issue 46, 2015
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Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework

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Abstract

A three dimensional (3D) cationic Metal–Organic Framework (MOF) has been fabricated from a neutral N-donor ligand and Cd(ClO4)2. The cationic MOF shows guest triggered inherent dynamic behaviour at room temperature. A single-crystal-to-single-crystal (SCSC) transformation experiment enabled the guest dependent structural dynamism to be well understood. The framework also displays facile anion exchange behaviour and anion dependent structural dynamism.

Graphical abstract: Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework

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Publication details

The article was received on 21 Jan 2015, accepted on 05 Mar 2015 and first published on 09 Mar 2015


Article type: Communication
DOI: 10.1039/C5CE00139K
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CrystEngComm, 2015,17, 8796-8800
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    Single-crystal-to-single-crystal transformation of an anion exchangeable dynamic metal–organic framework

    B. Manna, A. V. Desai, N. Kumar, A. Karmakar and S. K. Ghosh, CrystEngComm, 2015, 17, 8796
    DOI: 10.1039/C5CE00139K

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