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Issue 91, 2015
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Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

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Abstract

Phenyl rings in phenyl- or phenyl-alkylphosphines are selectively deuterated at the ortho position using Ru/PVP nanoparticles, while are fully reduced in the case of arylphosphine oxide derivatives and do not react in the case of arylphosphite. This different behavior provides information about the coordination mode of each ligand.

Graphical abstract: Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

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Supplementary files

Article information


Submitted
19 Aug 2015
Accepted
11 Sep 2015
First published
11 Sep 2015

Chem. Commun., 2015,51, 16342-16345
Article type
Communication
Author version available

Selective catalytic deuteration of phosphorus ligands using ruthenium nanoparticles: a new approach to gain information on ligand coordination

E. Bresó-Femenia, C. Godard, C. Claver, B. Chaudret and S. Castillón, Chem. Commun., 2015, 51, 16342
DOI: 10.1039/C5CC06984J

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