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Issue 92, 2015
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Cyclic enaminones. Part I: stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods

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Abstract

Cyclic enaminones are versatile intermediates to construct a variety of azacyclic frameworks and have been widely used in alkaloid synthesis. Here, we summarize three approaches for stereoselective syntheses of cyclic enaminones and their functionalized derivatives. These include chiral substrates (chirons) as starting materials, syntheses employing non-catalytic (stoichiometric) reagents, and catalytic asymmetric methods.

Graphical abstract: Cyclic enaminones. Part I: stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods

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Publication details

The article was received on 15 Jul 2015, accepted on 13 Oct 2015 and first published on 22 Oct 2015


Article type: Feature Article
DOI: 10.1039/C5CC05891K
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Citation: Chem. Commun., 2015,51, 16437-16449
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    Cyclic enaminones. Part I: stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods

    A. K. Chattopadhyay and S. Hanessian, Chem. Commun., 2015, 51, 16437
    DOI: 10.1039/C5CC05891K

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