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Issue 92, 2015
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Cyclic enaminones. Part I: stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods

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Abstract

Cyclic enaminones are versatile intermediates to construct a variety of azacyclic frameworks and have been widely used in alkaloid synthesis. Here, we summarize three approaches for stereoselective syntheses of cyclic enaminones and their functionalized derivatives. These include chiral substrates (chirons) as starting materials, syntheses employing non-catalytic (stoichiometric) reagents, and catalytic asymmetric methods.

Graphical abstract: Cyclic enaminones. Part I: stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods

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Article information


Submitted
15 Jul 2015
Accepted
13 Oct 2015
First published
22 Oct 2015

Chem. Commun., 2015,51, 16437-16449
Article type
Feature Article
Author version available

Cyclic enaminones. Part I: stereocontrolled synthesis using diastereoselective and catalytic asymmetric methods

A. K. Chattopadhyay and S. Hanessian, Chem. Commun., 2015, 51, 16437
DOI: 10.1039/C5CC05891K

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