A β-diketiminato magnesium alkyl complex is shown to be an effective pre-catalyst for the first reported catalytic hydroboration of organic isonitriles, RNC, with HBpin. The reaction proceeds under mild conditions when R = alkyl and provides access to the corresponding 1,2-diborylated amine products.
C. Weetman, M. S. Hill and M. F. Mahon, Chem. Commun., 2015, 51, 14477 DOI: 10.1039/C5CC05708F
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