Issue 77, 2015
From the journal:

Chemical Communications

Chiral template induced homochiral MOFs built from achiral components: SHG enhancement and enantioselective sensing of chiral alkamines by ion-exchange†

Yun-Hu Han,ab   Yue-Cheng Liu,a   Xiu-Shuang Xing,ac   Chong-Bin Tian,a   Ping Lina  and  Shao-Wu Du*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: swdu@fjirsm.ac.cn

b Graduate University of Chinese Academy of Sciences, Bejing 100039, P. R. China

c College of Chemistry, Fuzhou University, Fuzhou 350108, P. R. China

Abstract

A pair of chiral template induced anionic homochiral frameworks constructed from achiral components has been synthesized. Ion-exchange of counter cations with polar or chiral organic cations enhances the SHG efficiency of the frameworks. The enantioselective sensing of chiral alkamines can be achieved by the SHG response.

Graphical abstract: Chiral template induced homochiral MOFs built from achiral components: SHG enhancement and enantioselective sensing of chiral alkamines by ion-exchange

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Article information

DOI
https://doi.org/10.1039/C5CC05566K
Article type
Communication
Submitted
06 Jul 2015
Accepted
06 Aug 2015
First published
06 Aug 2015

Chem. Commun., 2015,51, 14481-14484

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Chiral template induced homochiral MOFs built from achiral components: SHG enhancement and enantioselective sensing of chiral alkamines by ion-exchange

Y. Han, Y. Liu, X. Xing, C. Tian, P. Lin and S. Du, Chem. Commun., 2015, 51, 14481 DOI: 10.1039/C5CC05566K

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