Issue 67, 2015
From the journal:

Chemical Communications

Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex†

Saet Byeol Kim,a   Dong Woo Lee,a   Suk-Kyu Changa  and  Kang Min Ok*a  

* Corresponding authors

a Department of Chemistry, Chung-Ang University, Seoul 156-756, Republic of Korea
E-mail: kmok@cau.ac.kr
Fax: +82 2 825 4736
Tel: +82 2 820 5197

Abstract

An unprecedented layered Pb-Kemp's triacid compound, Pb3[C6(CH3)3(CO2)3H6]2[DMF]3, has been synthesized. The material exhibits a selective CO2 adsorption, a reversible DMF coordination, and an intercalative hexanal addition reaction. A competing crystallization reaction under solvothermal conditions using Pb2+ and Cd2+ with Kemp's triacid reveals higher selectivity of Cd2+ over Pb2+.

Graphical abstract: Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5CC05360A
Article type
Communication
Submitted
30 Jun 2015
Accepted
15 Jul 2015
First published
15 Jul 2015

Chem. Commun., 2015,51, 13166-13169

Permissions

Request permissions

Pb3[C6(CH3)3(CO2)3H6]2[DMF]3: first layered Pb-Kemp's triacid complex

S. B. Kim, D. W. Lee, S. Chang and K. M. Ok, Chem. Commun., 2015, 51, 13166 DOI: 10.1039/C5CC05360A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements