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Issue 63, 2015
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A recyclable CO surrogate in regioselective alkoxycarbonylation of alkenes: indirect use of carbon dioxide

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Abstract

Herein, we report a Pd-catalysed alkoxycarbonylation of alkenes based on the use of a recyclable CO2 reduction product, the crystalline and air-stable N-formylsaccharin, as a CO surrogate. The carbonylation proceeds under ambient conditions in an exceptionally complementary regioselective fashion yielding the desired branched products from styrene derivatives and valuable linear esters from alkyl-substituted alkenes.

Graphical abstract: A recyclable CO surrogate in regioselective alkoxycarbonylation of alkenes: indirect use of carbon dioxide

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Publication details

The article was received on 17 Jun 2015, accepted on 02 Jul 2015 and first published on 02 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC05012J
Chem. Commun., 2015,51, 12574-12577
  • Open access: Creative Commons BY license
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    A recyclable CO surrogate in regioselective alkoxycarbonylation of alkenes: indirect use of carbon dioxide

    P. H. Gehrtz, V. Hirschbeck and I. Fleischer, Chem. Commun., 2015, 51, 12574
    DOI: 10.1039/C5CC05012J

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