Issue 57, 2015
From the journal:

Chemical Communications

Copper(i) complexes as alternatives to iridium(iii) complexes for highly efficient oxygen sensing†

Santiago Medina-Rodríguez,ab   Francisco J. Orriach-Fernández,b   Christopher Poole,c   Prashant Kumar,c   Ángel de la Torre-Vega,*a   Jorge F. Fernández-Sánchez,*b   Etienne Baranoff*c  and  Alberto Fernández-Gutiérrezb  

* Corresponding authors

a Department of Signal Theory, Networking and Communications, CITIC-UGR, University of Granada, C/ Periodista Rafael Gómez 2, E-18071 Granada, Spain
E-mail: atv@ugr.es

b Department of Analytical Chemistry, Faculty of Sciences, University of Granada, Avda. Fuentenueva s/n, E-18071 Granada, Spain
E-mail: jffernan@ugr.es

c School of Chemistry, University of Birmingham, Edgbaston, England, UK
E-mail: e.baranoff@bham.ac.uk

Abstract

The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa−1 between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa−1 between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.

Graphical abstract: Copper(i) complexes as alternatives to iridium(iii) complexes for highly efficient oxygen sensing

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Article information

DOI
https://doi.org/10.1039/C5CC04326C
Article type
Communication
Submitted
26 May 2015
Accepted
10 Jun 2015
First published
10 Jun 2015
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 11401-11404

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Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing

S. Medina-Rodríguez, F. J. Orriach-Fernández, C. Poole, P. Kumar, Á. de la Torre-Vega, J. F. Fernández-Sánchez, E. Baranoff and A. Fernández-Gutiérrez, Chem. Commun., 2015, 51, 11401 DOI: 10.1039/C5CC04326C

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