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Issue 57, 2015
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Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing

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Abstract

The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa−1 between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa−1 between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.

Graphical abstract: Copper(i) complexes as alternatives to iridium(iii) complexes for highly efficient oxygen sensing

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Publication details

The article was received on 26 May 2015, accepted on 10 Jun 2015 and first published on 10 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC04326C
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Citation: Chem. Commun., 2015,51, 11401-11404
  • Open access: Creative Commons BY-NC license
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    Copper(I) complexes as alternatives to iridium(III) complexes for highly efficient oxygen sensing

    S. Medina-Rodríguez, F. J. Orriach-Fernández, C. Poole, P. Kumar, Á. de la Torre-Vega, J. F. Fernández-Sánchez, E. Baranoff and A. Fernández-Gutiérrez, Chem. Commun., 2015, 51, 11401
    DOI: 10.1039/C5CC04326C

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