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Issue 71, 2015
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A non-regular layer arrangement of a pillared-layer coordination polymer: avoiding interpenetration via symmetry breaking at nodes

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Abstract

A coordination terpolymerization strategy is introduced to alter the connectivity within layers of a pillared-layer coordination polymer. Assembling two different dicarboxylate linkers around a metal cluster in the layer suppresses interpenetration while enabling formation of a rectangular 2D grid structure.

Graphical abstract: A non-regular layer arrangement of a pillared-layer coordination polymer: avoiding interpenetration via symmetry breaking at nodes

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Publication details

The article was received on 21 May 2015, accepted on 17 Jul 2015 and first published on 27 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC04223B
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Citation: Chem. Commun., 2015,51, 13611-13614
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    A non-regular layer arrangement of a pillared-layer coordination polymer: avoiding interpenetration via symmetry breaking at nodes

    A. Dutta, J. Ma, A. G. Wong-Foy and A. J. Matzger, Chem. Commun., 2015, 51, 13611
    DOI: 10.1039/C5CC04223B

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