Issue 71, 2015

A non-regular layer arrangement of a pillared-layer coordination polymer: avoiding interpenetration via symmetry breaking at nodes

Abstract

A coordination terpolymerization strategy is introduced to alter the connectivity within layers of a pillared-layer coordination polymer. Assembling two different dicarboxylate linkers around a metal cluster in the layer suppresses interpenetration while enabling formation of a rectangular 2D grid structure.

Graphical abstract: A non-regular layer arrangement of a pillared-layer coordination polymer: avoiding interpenetration via symmetry breaking at nodes

Supplementary files

Article information

Article type
Communication
Submitted
21 May 2015
Accepted
17 Jul 2015
First published
27 Jul 2015

Chem. Commun., 2015,51, 13611-13614

Author version available

A non-regular layer arrangement of a pillared-layer coordination polymer: avoiding interpenetration via symmetry breaking at nodes

A. Dutta, J. Ma, A. G. Wong-Foy and A. J. Matzger, Chem. Commun., 2015, 51, 13611 DOI: 10.1039/C5CC04223B

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