Issue 59, 2015
From the journal:

Chemical Communications

Organocatalytic asymmetric reaction of indol-2-yl carbinols with enamides: synthesis of chiral 2-indole-substituted 1,1-diarylalkanes†

Chao-You Liuab  and  Fu-She Han*ac  

* Corresponding authors

a Key Lab of Synthetic Rubber, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, China
E-mail: fshan@ciac.ac.cn

b The University of Chinese Academy of Sciences, Beijing 100864, China

c State Key Lab of Fine Chemicals, Dalian University of Technology, Dalian, China

Abstract

The chiral phosphoramide-catalyzed asymmetric reaction of indol-2-yl carbinols with enamides is presented. The method provided an efficient and novel way for the synthesis of chiral 2-indole-substituted 1,1-diarylalkane derivatives.

Graphical abstract: Organocatalytic asymmetric reaction of indol-2-yl carbinols with enamides: synthesis of chiral 2-indole-substituted 1,1-diarylalkanes

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Article information

DOI
https://doi.org/10.1039/C5CC03345D
Article type
Communication
Submitted
22 Apr 2015
Accepted
12 Jun 2015
First published
12 Jun 2015

Chem. Commun., 2015,51, 11844-11847

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Organocatalytic asymmetric reaction of indol-2-yl carbinols with enamides: synthesis of chiral 2-indole-substituted 1,1-diarylalkanes

C. Liu and F. Han, Chem. Commun., 2015, 51, 11844 DOI: 10.1039/C5CC03345D

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