Issue 59, 2015
From the journal:

Chemical Communications

Rhodium(iii)-catalyzed cyanation of vinylic C–H bonds: N-cyano-N-phenyl-p-toluenesulfonamide as a cyanation reagent†

Wei Su,‡a   Tian-Jun Gong,‡a   Bin Xiaoa  and  Yao Fu*a  

* Corresponding authors

a iChEM, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China
E-mail: fuyao@ustc.edu.cn

Abstract

Rh(III)-catalyzed direct vinylic C–H cyanation reaction has been developed as a practical method for the synthesis of alkenyl nitriles. N-Cyano-N-phenyl-p-methylbenzenesulfonamide (NCTS), a user-friendly cyanation reagent, was used in the transformation. Both acrylamides and ketoximes can be employed in the new C–H cyanation process.

Graphical abstract: Rhodium(iii)-catalyzed cyanation of vinylic C–H bonds: N-cyano-N-phenyl-p-toluenesulfonamide as a cyanation reagent

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Article information

DOI
https://doi.org/10.1039/C4CC09790D
Article type
Communication
Submitted
08 Dec 2014
Accepted
12 Jun 2015
First published
12 Jun 2015

Chem. Commun., 2015,51, 11848-11851

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Rhodium(III)-catalyzed cyanation of vinylic C–H bonds: N-cyano-N-phenyl-p-toluenesulfonamide as a cyanation reagent

W. Su, T. Gong, B. Xiao and Y. Fu, Chem. Commun., 2015, 51, 11848 DOI: 10.1039/C4CC09790D

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