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Issue 60, 2015
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Polymer@MOF@MOF: “grafting from” atom transfer radical polymerization for the synthesis of hybrid porous solids

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Abstract

The application of a core–shell architecture allows the formation of a polymer-coated metal–organic framework (MOF) maintaining high surface area (2289–2857 m2 g−1). The growth of a MOF shell from a MOF core was used to spatially localize initiators by post-synthetic modification. The confinement of initiators ensures that polymerization is restricted to the outer shell of the MOF.

Graphical abstract: Polymer@MOF@MOF: “grafting from” atom transfer radical polymerization for the synthesis of hybrid porous solids

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Publication details

The article was received on 12 Apr 2015, accepted on 22 Jun 2015 and first published on 22 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC03027G
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Citation: Chem. Commun., 2015,51, 11994-11996
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    Polymer@MOF@MOF: “grafting from” atom transfer radical polymerization for the synthesis of hybrid porous solids

    K. A. McDonald, J. I. Feldblyum, K. Koh, A. G. Wong-Foy and A. J. Matzger, Chem. Commun., 2015, 51, 11994
    DOI: 10.1039/C5CC03027G

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