Issue 60, 2015

Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks

Abstract

The assembly of two-dimensional (2D) large channel uranyl–organic polyrotaxane networks as well as structural regulation of uranyl-bearing units using jointed cucurbit[6]uril-based pseudorotaxanes with integral rigidity based on supramolecular inclusion is presented for the first time. This construction strategy concerning controlling molecular integral rigidity based on supramolecular inclusion may afford an entirely new methodology for coordination chemistry.

Graphical abstract: Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks

Supplementary files

Article information

Article type
Communication
Submitted
30 May 2015
Accepted
19 Jun 2015
First published
22 Jun 2015

Chem. Commun., 2015,51, 11990-11993

Supramolecular inclusion-based molecular integral rigidity: a feasible strategy for controlling the structural connectivity of uranyl polyrotaxane networks

L. Mei, L. Wang, L. Yuan, S. An, Y. Zhao, Z. Chai, P. C. Burns and W. Shi, Chem. Commun., 2015, 51, 11990 DOI: 10.1039/C5CC04409J

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