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Issue 67, 2015
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Engineering two-dimensional hybrid NaCl–organic coordinated nanoarchitectures on metal surfaces

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Abstract

We selectively engineer three two-dimensional self-assembled hybrid PTCDI–NaCl nanoarchitectures, i.e. a flower-structure, a mesh-structure and a chain-structure on Au(111). Scanning tunneling microscopy reveals that NaCl-dimers selectively interact with molecular N–H groups. The PTCDI⋯NaCl-dimer binding appears to be highly directional. Hybrid molecular-ionic self-assembly is a promising alternative to metal-coordinated and multicomponent organic nanostructures to engineer novel nanoarchitectures on surfaces.

Graphical abstract: Engineering two-dimensional hybrid NaCl–organic coordinated nanoarchitectures on metal surfaces

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Publication details

The article was received on 05 Mar 2015, accepted on 03 Jul 2015 and first published on 06 Jul 2015


Article type: Communication
DOI: 10.1039/C5CC01892G
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Chem. Commun., 2015,51, 13162-13165

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    Engineering two-dimensional hybrid NaCl–organic coordinated nanoarchitectures on metal surfaces

    J. Hieulle, D. Peyrot, Z. Jiang and F. Silly, Chem. Commun., 2015, 51, 13162
    DOI: 10.1039/C5CC01892G

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