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Issue 54, 2015
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Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

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Abstract

A mesoionic carbene with a ferrocene backbone is used as a metalloligand to generate the first example of their Fe–Au heterobimetallic complexes. The details of geometric and electronic structures in different redox states and preliminary catalytic results are presented.

Graphical abstract: Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

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Article information


Submitted
21 Feb 2015
Accepted
28 May 2015
First published
28 May 2015

This article is Open Access

Chem. Commun., 2015,51, 10949-10952
Article type
Communication

Heterobimetallic complexes with redox-active mesoionic carbenes as metalloligands: electrochemical properties, electronic structures and catalysis

L. Hettmanczyk, S. Manck, C. Hoyer, S. Hohloch and B. Sarkar, Chem. Commun., 2015, 51, 10949
DOI: 10.1039/C5CC01578B

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