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Issue 19, 2015
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Platinum polyoxoniobates

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Reaction of [Nb6O19]8− with [Pt(OH)4(H2O)2] upon heating yielded first characterized platinum polyniobates. A dimeric complex [Nb6O19{Pt(OH)2}]212− (1) is produced in a 1 : 1 molar ratio. Increasing the Pt/Nb6 molar ratio to 1 : 2 yields a mixture of 1 and a sandwich-type complex [Pt(Nb6O19)2]12− (2).

Graphical abstract: Platinum polyoxoniobates

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The article was received on 13 Jan 2015, accepted on 22 Jan 2015 and first published on 22 Jan 2015

Article type: Communication
DOI: 10.1039/C5CC00315F
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Citation: Chem. Commun., 2015,51, 4021-4023
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    Platinum polyoxoniobates

    P. A. Abramov, C. Vicent, N. B. Kompankov, A. L. Gushchin and M. N. Sokolov, Chem. Commun., 2015, 51, 4021
    DOI: 10.1039/C5CC00315F

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