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Issue 16, 2015
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AsCat and FurCat: new Pd catalysts for selective room-temperature Stille cross-couplings of benzyl chlorides with organostannanes

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Abstract

Two novel succinimide-based palladium complexes, AsCat and FurCat, are highly efficient catalysts for room-temperature Stille cross-coupling of organostannanes with benzyl chlorides. The air- and moisture-stable catalysts are prepared in one step, and the coupling reactions proceed with a high selectivity for the benzyl position under mild conditions without the need for additives.

Graphical abstract: AsCat and FurCat: new Pd catalysts for selective room-temperature Stille cross-couplings of benzyl chlorides with organostannanes

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Publication details

The article was received on 08 Dec 2014, accepted on 14 Jan 2015 and first published on 28 Jan 2015


Article type: Communication
DOI: 10.1039/C4CC09810B
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Chem. Commun., 2015,51, 3466-3469

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    AsCat and FurCat: new Pd catalysts for selective room-temperature Stille cross-couplings of benzyl chlorides with organostannanes

    T. O. Ronson, J. R. Carney, A. C. Whitwood, R. J. K. Taylor and I. J. S. Fairlamb, Chem. Commun., 2015, 51, 3466
    DOI: 10.1039/C4CC09810B

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