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Issue 16, 2015
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A robust and modular synthesis of ynamides

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Abstract

A flexible, modular ynamide synthesis is reported that uses trichloroethene as an inexpensive two carbon synthon. A wide range of amides and electrophiles can be converted to the corresponding ynamides, importantly including acyclic carbamates, hindered amides, and aryl amides. This method thus overcomes many of the limitations of other approaches to this useful functionality.

Graphical abstract: A robust and modular synthesis of ynamides

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Supplementary files

Article information


Submitted
07 Oct 2014
Accepted
29 Oct 2014
First published
06 Nov 2014

This article is Open Access

Chem. Commun., 2015,51, 3316-3319
Article type
Communication
Author version available

A robust and modular synthesis of ynamides

S. J. Mansfield, C. D. Campbell, M. W. Jones and E. A. Anderson, Chem. Commun., 2015, 51, 3316
DOI: 10.1039/C4CC07876D

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