Issue 13, 2015
From the journal:

Chemical Communications

Dependence of crystal size on the catalytic performance of a porous coordination polymer†

Tomokazu Kiyonaga,a   Masakazu Higuchi,ab   Takashi Kajiwara,a   Yohei Takashima,a   Jingui Duan,a   Kazuro Nagashimac  and  Susumu Kitagawa*ad  

* Corresponding authors

a Institute for Integrated Cell-Material Sciences (iCeMS), Kyoto University, Yoshida Ushinomiyacho, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: kitagawa@icems.kyoto-u.ac.jp

b Japan Science and Technology Agency, PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan

c Shoei Chemical Inc., 5 Azawakasa, Fujikicho, Tosu, Saga 841-0048, Japan
E-mail: k-nagashima@shoeichem.co.jp

d Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

Submicrosized MOF-76(Yb) exhibits a higher catalytic performance for esterification than microsized MOF-76(Yb). Control of the crystal size of porous heterogeneous catalysts, such as PCP/MOFs, offers a promising approach to fabricating high-performance catalysts based on accessibility to the internal catalytic sites.

Graphical abstract: Dependence of crystal size on the catalytic performance of a porous coordination polymer

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Article information

DOI
https://doi.org/10.1039/C4CC07562E
Article type
Communication
Submitted
25 Sep 2014
Accepted
11 Dec 2014
First published
11 Dec 2014

Chem. Commun., 2015,51, 2728-2730

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Dependence of crystal size on the catalytic performance of a porous coordination polymer

T. Kiyonaga, M. Higuchi, T. Kajiwara, Y. Takashima, J. Duan, K. Nagashima and S. Kitagawa, Chem. Commun., 2015, 51, 2728 DOI: 10.1039/C4CC07562E

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