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Abstract | Cited by

A highly efficient CH3CN-promoted hexamethyldisilazane per-O-trimethylsilylation of amino sugars was developed. Its applications in homogenous N-functionalisation and a concise synthesis of glucosamine 6-phosphate are described.

Graphical abstract: Chemoselective per-O-trimethylsilylation and homogeneous N-functionalisation of amino sugars

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