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Issue 10, 2015
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Dynamic behaviour of monohaptoallylpalladium species: internal coordination as a driving force in allylic alkylation chemistry

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Abstract

Contemporary catalytic procedures involving alkylpalladium(II) have enriched the arsenal of synthetic organic chemistry. Those transformations usually rely on internal coordination through “directing groups”, carefully designed to maximize catalytic efficiency and regioselectivity. Herein, we report structural and reactivity studies of a series of internally coordinated monohaptoallylpalladium complexes. These species enable the direct spectroscopic observation and theoretical study of π–σ–π interconversion processes. They further display unusual dynamic behavior which should be of direct relevance to chemistries beyond catalytic allylic alkylation.

Graphical abstract: Dynamic behaviour of monohaptoallylpalladium species: internal coordination as a driving force in allylic alkylation chemistry

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Publication details

The article was received on 23 May 2015, accepted on 03 Jul 2015 and first published on 06 Jul 2015


Article type: Edge Article
DOI: 10.1039/C5SC01867F
Chem. Sci., 2015,6, 5734-5739
  • Open access: Creative Commons BY license
    All publication charges for this article have been paid for by the Royal Society of Chemistry

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    Dynamic behaviour of monohaptoallylpalladium species: internal coordination as a driving force in allylic alkylation chemistry

    L. Xie, V. Bagutski, D. Audisio, L. M. Wolf, V. Schmidts, K. Hofmann, C. Wirtz, W. Thiel, C. M. Thiele and N. Maulide, Chem. Sci., 2015, 6, 5734
    DOI: 10.1039/C5SC01867F

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