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Issue 7, 2015
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A single crystalline porphyrinic titanium metal–organic framework

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Abstract

We successfully assembled the photocatalytic titanium-oxo cluster and photosensitizing porphyrinic linker into a metal–organic framework (MOF), namely PCN-22. A preformed titanium-oxo carboxylate cluster is adopted as the starting material to judiciously control the MOF growth process to afford single crystals. This synthetic method is useful to obtain highly crystalline titanium MOFs, which has been a daunting challenge in this field. Moreover, PCN-22 demonstrated permanent porosity and photocatalytic activities toward alcohol oxidation.

Graphical abstract: A single crystalline porphyrinic titanium metal–organic framework

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Publication details

The article was received on 13 Mar 2015, accepted on 28 Apr 2015 and first published on 28 Apr 2015


Article type: Edge Article
DOI: 10.1039/C5SC00916B
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Chem. Sci., 2015,6, 3926-3930
  • Open access: Creative Commons BY license
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    A single crystalline porphyrinic titanium metal–organic framework

    S. Yuan, T. Liu, D. Feng, J. Tian, K. Wang, J. Qin, Q. Zhang, Y. Chen, M. Bosch, L. Zou, S. J. Teat, S. J. Dalgarno and H. Zhou, Chem. Sci., 2015, 6, 3926
    DOI: 10.1039/C5SC00916B

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