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Issue 82, 2015
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Chrysaorenes: assembling coronoid hydrocarbons via the fold-in synthesis

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Abstract

Two coronoid hydrocarbons, [3]- and [4]chrysaorene were synthesized from fluorenophane precursors using the fold-in strategy. [3]Chrysaorene is a bowl-shaped fragment of the C240-Ih fullerene, whereas [4]chrysaorene is planar and contains a unique large 24-membered internal ring. The chrysaorenes show geometry-dependent magnetic properties and are strongly fluorescent.

Graphical abstract: Chrysaorenes: assembling coronoid hydrocarbons via the fold-in synthesis

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Article information


Submitted
20 Jul 2015
Accepted
14 Aug 2015
First published
19 Aug 2015

Chem. Commun., 2015,51, 15094-15097
Article type
Communication
Author version available

Chrysaorenes: assembling coronoid hydrocarbons via the fold-in synthesis

M. A. Majewski, T. Lis, J. Cybińska and M. Stępień, Chem. Commun., 2015, 51, 15094
DOI: 10.1039/C5CC06046J

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