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Issue 82, 2015
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Enhanced luminescence stability with a Tb–spin crossover nanocomposite for spin state monitoring

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Abstract

[Fe(Htrz)2(trz)]BF4@SiO2 nanorods were synthesized using a reverse emulsion technique and a Tb3+ complex was chemically bound to the silica surface. This Tb–spin crossover nanocomposite demonstrates high luminescence stability under continuous thermal cycling. A reabsorption mechanism is determined to be responsible for the luminescence intensity variation during the spin state switching of the iron complex.

Graphical abstract: Enhanced luminescence stability with a Tb–spin crossover nanocomposite for spin state monitoring

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Publication details

The article was received on 31 Jul 2015, accepted on 25 Aug 2015 and first published on 25 Aug 2015


Article type: Communication
DOI: 10.1039/C5CC06426K
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Citation: Chem. Commun., 2015,51, 15098-15101
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    Enhanced luminescence stability with a Tb–spin crossover nanocomposite for spin state monitoring

    I. Suleimanov, O. Kraieva, G. Molnár, L. Salmon and A. Bousseksou, Chem. Commun., 2015, 51, 15098
    DOI: 10.1039/C5CC06426K

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