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Issue 72, 2015
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Cu-Catalyzed direct cyanation of terminal alkynes with AMBN or AIBN as the cyanation reagent

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Abstract

A Cu-catalyzed direct cyanation of terminal alkynes was reported with broad substrate generality in moderate to high yield, and AMBN (azobisisoamylonitrile)/AIBN (azobisisobutyronitrile) were used as less toxic and effective cyanating sources in open air. Interestingly, addition products were selectively achieved as the major product under the same conditions in argon.

Graphical abstract: Cu-Catalyzed direct cyanation of terminal alkynes with AMBN or AIBN as the cyanation reagent

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Supplementary files

Article information


Submitted
18 Jun 2015
Accepted
23 Jul 2015
First published
24 Jul 2015

Chem. Commun., 2015,51, 13822-13825
Article type
Communication
Author version available

Cu-Catalyzed direct cyanation of terminal alkynes with AMBN or AIBN as the cyanation reagent

G. Rong, J. Mao, Y. Zheng, R. Yao and X. Xu, Chem. Commun., 2015, 51, 13822 DOI: 10.1039/C5CC04987C

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