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Issue 69, 2015
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Rh-catalyzed oxidizing group-directed ortho C–H vinylation of arenes by vinylstannanes

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Abstract

An efficient method for the synthesis of functionalized vinyl arenes from the reaction of N-methoxybenzamides or N-phenoxyacetamides with vinylstannanes via rhodium(III)-catalyzed C–H activation is described. The application of the methodology for the synthesis of a natural product thalactamine and a 7-membered ring oxepine are also demonstrated.

Graphical abstract: Rh-catalyzed oxidizing group-directed ortho C–H vinylation of arenes by vinylstannanes

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Article information


Submitted
21 May 2015
Accepted
10 Jun 2015
First published
10 Jun 2015

Chem. Commun., 2015,51, 13362-13364
Article type
Communication

Rh-catalyzed oxidizing group-directed ortho C–H vinylation of arenes by vinylstannanes

S. Prakash, K. Muralirajan and C. Cheng, Chem. Commun., 2015, 51, 13362
DOI: 10.1039/C5CC04211A

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