SCHEDULED MAINTENANCE
An efficient method for the synthesis of functionalized vinyl arenes from the reaction of N-methoxybenzamides or N-phenoxyacetamides with vinylstannanes via rhodium(III)-catalyzed C–H activation is described. The application of the methodology for the synthesis of a natural product thalactamine and a 7-membered ring oxepine are also demonstrated.
S. Prakash, K. Muralirajan and C. Cheng, Chem. Commun., 2015, 51, 13362 DOI: 10.1039/C5CC04211A
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