Issue 59, 2015

Artificial light-harvesting arrays for solar energy conversion

Abstract

Solar fuel production, the process whereby an energy-rich substance is produced using electrons provided by water under exposure to sunlight, requires the cooperative accumulation of multiple numbers of photons. Identifying the optimum reagents is a difficult challenge, even without imposing the restriction that these same materials must function as both sensitiser and catalyst. The blockade caused by an inadequate supply of photons at the catalytic sites might be resolved by making use of an artificial light-harvesting array whose sole purpose is to funnel photons of appropriate frequency to the active catalyst, which can now be a dark reagent. Here we consider several types of artificial photon collectors built from fluorescent modules interconnected via electronic energy transfer. Emphasis is placed on the materials aspects and on establishing the basic operating principles.

Graphical abstract: Artificial light-harvesting arrays for solar energy conversion

Article information

Article type
Feature Article
Submitted
29 Apr 2015
Accepted
09 Jun 2015
First published
09 Jun 2015

Chem. Commun., 2015,51, 11745-11756

Author version available

Artificial light-harvesting arrays for solar energy conversion

A. Harriman, Chem. Commun., 2015, 51, 11745 DOI: 10.1039/C5CC03577E

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