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Issue 27, 2015
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Effective separation of the actinides Am(iii) and Cm(iii) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines

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Abstract

It has been shown that modification of the phenanthroline backbone of CyMe4-BTPhen leads to subtle electronic modulation, permitting differential ligation of Am(III) and Cm(III) resulting in separation factors up to 7.

Graphical abstract: Effective separation of the actinides Am(iii) and Cm(iii) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines

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Publication details

The article was received on 20 Jan 2015, accepted on 25 Feb 2015 and first published on 25 Feb 2015


Article type: Communication
DOI: 10.1039/C5CC00567A
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Chem. Commun., 2015,51, 5860-5863

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    Effective separation of the actinides Am(III) and Cm(III) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines

    A. Afsar, L. M. Harwood, M. J. Hudson, J. Westwood and A. Geist, Chem. Commun., 2015, 51, 5860
    DOI: 10.1039/C5CC00567A

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