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Issue 11, 2015
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A Rh-catalyzed 1,2-sulfur migration/aza-Diels–Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles

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Abstract

A novel Rh(II) catalyzed intramolecular 1,2-sulfur rearrangement/intermolecular aza-Diels–Alder cascade initiated by azavinyl carbenes has been developed, efficiently affording sulfur-containing tetrahydropyridine derivatives or α,β-unsaturated imines with a broad substrate scope.

Graphical abstract: A Rh-catalyzed 1,2-sulfur migration/aza-Diels–Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles

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Supplementary files

Article information


Submitted
05 Nov 2014
Accepted
13 Dec 2014
First published
17 Dec 2014

Chem. Commun., 2015,51, 2122-2125
Article type
Communication
Author version available

A Rh-catalyzed 1,2-sulfur migration/aza-Diels–Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles

Y. Jiang, X. Tang and M. Shi, Chem. Commun., 2015, 51, 2122 DOI: 10.1039/C4CC08829H

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