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Issue 1, 2015
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Chemoselective per-O-trimethylsilylation and homogeneous N-functionalisation of amino sugars

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Abstract

A highly efficient CH3CN-promoted hexamethyldisilazane per-O-trimethylsilylation of amino sugars was developed. Its applications in homogenous N-functionalisation and a concise synthesis of glucosamine 6-phosphate are described.

Graphical abstract: Chemoselective per-O-trimethylsilylation and homogeneous N-functionalisation of amino sugars

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Article information


Submitted
23 Aug 2014
Accepted
04 Nov 2014
First published
04 Nov 2014

Chem. Commun., 2015,51, 104-106
Article type
Communication
Author version available

Chemoselective per-O-trimethylsilylation and homogeneous N-functionalisation of amino sugars

A. A. Joseph, V. M. Dhurandhare, C. Chang, V. P. Verma, G. P. Mishra, C. Ku, C. Lin and C. Wang, Chem. Commun., 2015, 51, 104
DOI: 10.1039/C4CC06645F

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