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Issue 86, 2014
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Chemodosimeter for fluoride ions based on F-triggered Si–O cleavage followed by the deprotonation/autoxidation of secondary nitrile C–H group

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Abstract

A completely new strategy for a chemodosimeter for fluoride based on F-triggered Si–O bond cleavage, followed by the deprotonation/autoxidation of secondary nitrile C–H group was developed for the first time. The chemodosimeter exhibited high selectivity and sensitivity, dramatic color “turn-on”, and fluorescence “turn-off” for the detection for fluoride.

Graphical abstract: Chemodosimeter for fluoride ions based on F−-triggered Si–O cleavage followed by the deprotonation/autoxidation of secondary nitrile C–H group

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Article information


Submitted
31 Jul 2014
Accepted
15 Sep 2014
First published
16 Sep 2014

RSC Adv., 2014,4, 46016-46019
Article type
Communication

Chemodosimeter for fluoride ions based on F-triggered Si–O cleavage followed by the deprotonation/autoxidation of secondary nitrile C–H group

B. Li, C. Zhang, C. Liu, J. Chen, X. Wang, Z. Liu and F. Yi, RSC Adv., 2014, 4, 46016
DOI: 10.1039/C4RA07870E

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