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Issue 5, 2014
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Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation

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Abstract

Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds, using Ru(bpy)3Cl2 as a photocatalyst and combining molecular oxygen and triphenylcarbenium as a new sacrificial acceptor, has been developed for carbon–carbon bond formation giving access to dimerization, allylation and polycyclization products.

Graphical abstract: Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation

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Publication details

The article was received on 13 Mar 2014, accepted on 29 Apr 2014 and first published on 30 Apr 2014


Article type: Research Article
DOI: 10.1039/C4QO00071D
Org. Chem. Front., 2014,1, 551-555

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    Visible-light photocatalytic oxidation of 1,3-dicarbonyl compounds and carbon–carbon bond formation

    M. Daniel, L. Fensterbank, J. Goddard and C. Ollivier, Org. Chem. Front., 2014, 1, 551
    DOI: 10.1039/C4QO00071D

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