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Issue 5, 2014
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Vanadium-catalyzed C(sp3)–H fluorination reactions

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Vanadium(III) oxide catalyzes the direct fluorination of C(sp3)–H groups with Selectfluor. This reaction is operationally simple. The catalyst and the reaction by-product can be removed easily by filtration. Using this method, a fluorine atom can be introduced to the tertiary position of 1,4-cineole and L-menthone selectively.

Graphical abstract: Vanadium-catalyzed C(sp3)–H fluorination reactions

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The article was received on 27 Feb 2014, accepted on 24 Mar 2014 and first published on 25 Mar 2014

Article type: Research Article
DOI: 10.1039/C4QO00057A
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Citation: Org. Chem. Front., 2014,1, 468-472
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    Vanadium-catalyzed C(sp3)–H fluorination reactions

    J. Xia, Y. Ma and C. Chen, Org. Chem. Front., 2014, 1, 468
    DOI: 10.1039/C4QO00057A

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