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Abstract | Cited by

The ring-opening polymerization (ROP) of L-lactide in dichloromethane with (+)-sparteine is described. Under aprotic conditions, (+)-sparteine leads to controlled cyclic polyesters mainly obtained by a backbiting process from the in situ generated tertiary amine-containing symmetrical binary zwitterion.

Graphical abstract: One-step synthesis of polylactide macrocycles from sparteine-initiated ROP

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