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Abstract | Cited by

Irradiation of three chromone-2-carboxamides with a chiral auxiliary resulted in diastereoselective formation of a C2-chiral anti-HH dimer scaffold. Selection of the solvent polarity and decreasing the temperature resulted in asymmetric induction with up to 84% diastereomeric excess (de).

Graphical abstract: Diastereoselective photodimerization reactions of chromone-2-carboxamides to construct a C2-chiral scaffold

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