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Issue 40, 2014
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Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

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Abstract

Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.

Graphical abstract: Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

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Publication details

The article was received on 24 Jul 2014, accepted on 01 Sep 2014 and first published on 02 Sep 2014


Article type: Communication
DOI: 10.1039/C4OB01570C
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Org. Biomol. Chem., 2014,12, 7927-7931

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    Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

    A. R. Kennedy, W. J. Kerr, R. Moir and M. Reid, Org. Biomol. Chem., 2014, 12, 7927
    DOI: 10.1039/C4OB01570C

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