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Issue 40, 2014
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Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

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Abstract

Synthesis of a series of iridium(I) complexes of the type [(COD)Ir(IMes)(PPh3)]X (X = BF4, OTf, and BArF) has been established. Application of these species in mild hydrogen isotope exchange processes revealed more efficient catalysis and, further, a wider solvent scope when employing larger, more weakly coordinating counterions.

Graphical abstract: Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

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Supplementary files

Article information


Submitted
24 Jul 2014
Accepted
01 Sep 2014
First published
02 Sep 2014

Org. Biomol. Chem., 2014,12, 7927-7931
Article type
Communication
Author version available

Anion effects to deliver enhanced iridium catalysts for hydrogen isotope exchange processes

A. R. Kennedy, W. J. Kerr, R. Moir and M. Reid, Org. Biomol. Chem., 2014, 12, 7927
DOI: 10.1039/C4OB01570C

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