Issue 23, 2014
From the journal:

Dalton Transactions

Pincer versus pseudopincer: isomerism in palladium(ii) complexes bearing κ3C,S,C ligands†

Jan Christopher Bernhammer,ab   Gilles Frison*b  and  Han Vinh Huynh*a  

* Corresponding authors

a Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore
E-mail: chmhhv@nus.edu.sg
Fax: +65 6779 1691
Tel: +65 6516 2670

b Laboratoire de Chimie Moleculaire, Department of Chemistry, Ecole Polytechnique and CNRS, 91128 Palaiseau Cedex, France
E-mail: gilles.frison@polytechnique.org
Fax: +331 6933 4803
Tel: +33 1 6933 4834

Abstract

In NHC pincer complexes incorporating a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.

Graphical abstract: Pincer versus pseudopincer: isomerism in palladium(ii) complexes bearing κ3C,S,C ligands

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Article information

DOI
https://doi.org/10.1039/C4DT01047G
Article type
Communication
Submitted
09 Apr 2014
Accepted
14 Apr 2014
First published
14 Apr 2014
This article is Open Access
Creative Commons BY license

Dalton Trans., 2014,43, 8591-8594

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Pincer versus pseudopincer: isomerism in palladium(II) complexes bearing κ3C,S,C ligands

J. C. Bernhammer, G. Frison and H. V. Huynh, Dalton Trans., 2014, 43, 8591 DOI: 10.1039/C4DT01047G

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