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Issue 12, 2014
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Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2] (M = Au, Ag)

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Abstract

The linear [M(CN)2] (M = Au, Ag) anions can be used as metalloligands in oxime-based Mn chemistry to afford 1D chains of [MnIII6] single-molecule magnets (SMMs).

Graphical abstract: Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2]− (M = Au, Ag)

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Supplementary files

Article information


Submitted
13 Dec 2013
Accepted
23 Jan 2014
First published
23 Jan 2014

Dalton Trans., 2014,43, 4622-4625
Article type
Communication
Author version available

Combining oxime-based [Mn6] clusters with cyanometalates: 1D chains of [Mn6] SMMs from [M(CN)2] (M = Au, Ag)

S. Sanz, J. M. Frost, G. Lorusso, M. Evangelisti, M. B. Pitak, S. J. Coles, G. S. Nichol and E. K. Brechin, Dalton Trans., 2014, 43, 4622
DOI: 10.1039/C3DT53502A

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