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Issue 2, 2015
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Observation of nondispersing classical-like molecular rotation

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Abstract

Using the technique of an optical centrifuge, we produce rotational wave packets which evolve in time along either classical-like or non-classical trajectories. After releasing O2 and D2 molecules from the centrifuge, we track their field-free rotation by monitoring the molecular angular distribution with velocity map imaging. Due to the dispersion of the created rotational wave packets in oxygen, we observe a gradual transition between “dumbbell”-shaped and “cross”-shaped distributions, both rotating with a classical rotation frequency. In deuterium, a much narrower rotational wave packet is produced and shown to evolve in a truly classical non-dispersing fashion.

Graphical abstract: Observation of nondispersing classical-like molecular rotation

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Article information


Submitted
01 Oct 2014
Accepted
13 Nov 2014
First published
14 Nov 2014

Phys. Chem. Chem. Phys., 2015,17, 951-956
Article type
Paper
Author version available

Observation of nondispersing classical-like molecular rotation

A. Korobenko, J. W. Hepburn and V. Milner, Phys. Chem. Chem. Phys., 2015, 17, 951
DOI: 10.1039/C4CP04434G

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