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Issue 18, 2014
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Ceria co-doping: synergistic or average effect?

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Abstract

Ceria (CeO2) co-doping has been suggested as a means to achieve ionic conductivities that are significantly higher than those in singly doped systems. Rekindled interest in this topic over the last decade has given rise to claims of much improved performance. The present study makes use of computer simulations to investigate the bulk ionic conductivity of rare earth (RE) doped ceria, where RE = Sc, Gd, Sm, Nd and La. The results from the singly doped systems are compared to those from ceria co-doped with Nd/Sm and Sc/La. The pattern that emerges from the conductivity data is consistent with the dominance of local lattice strains from individual defects, rather than the synergistic co-doping effect reported recently, and as a result, no enhancement in the conductivity of co-doped samples is observed.

Graphical abstract: Ceria co-doping: synergistic or average effect?

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Article information


Submitted
27 Feb 2014
Accepted
28 Feb 2014
First published
28 Feb 2014

Phys. Chem. Chem. Phys., 2014,16, 8320-8331
Article type
Paper
Author version available

Ceria co-doping: synergistic or average effect?

M. Burbano, S. Nadin, D. Marrocchelli, M. Salanne and G. W. Watson, Phys. Chem. Chem. Phys., 2014, 16, 8320
DOI: 10.1039/C4CP00856A

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