New heteropolyniobates based on a bicapped Keggin-type {VNb14} cluster with selective adsorption and photocatalytic properties

Peng Huang; En-Long Zhou; Xin-Long Wang; Chun-Yi Sun; Hai-Ning Wang; Yan Xing; Kui-Zhan Shao; Zhong-Min Su

doi:10.1039/C4CE00960F

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New heteropolyniobates based on a bicapped Keggin-type {VNb₁₄} cluster with selective adsorption and photocatalytic properties†

Peng Huang,^a En-Long Zhou,^a Xin-Long Wang,*^a Chun-Yi Sun,^a Hai-Ning Wang,^a Yan Xing,*^a Kui-Zhan Shao^a and Zhong-Min Su*^a

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* Corresponding authors

^a Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China
E-mail: wangxl824@nenu.edu.cn, zmsu@nenu.edu.cn, xingy202@nenu.edu.cn

Abstract

New heteropolyniobates based on a bicapped Keggin-type {VNb₁₄O₄₂(NO₃)₂} (abbreviated as {VNb₁₄}) cluster have been successfully synthesized by conventional aqueous methods. These clusters are a type of multifunctional material, which exhibit selective adsorption for methanol, ethanol and water and photocatalytic H₂ evolution activity.

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Article information

DOI: https://doi.org/10.1039/C4CE00960F
Article type: Communication
Submitted: 08 May 2014
Accepted: 20 Jun 2014
First published: 20 Jun 2014

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CrystEngComm, 2014,16, 9582-9585

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New heteropolyniobates based on a bicapped Keggin-type {VNb₁₄} cluster with selective adsorption and photocatalytic properties

P. Huang, E. Zhou, X. Wang, C. Sun, H. Wang, Y. Xing, K. Shao and Z. Su, CrystEngComm, 2014, 16, 9582 DOI: 10.1039/C4CE00960F

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