Issue 41, 2014
From the journal:

CrystEngComm

Enhanced water stability of a microporous acylamide-functionalized metal–organic framework via interpenetration and methyl decoration†

Baishu Zheng,*a   Xiu Lin,a   Zhaoxu Wang,*a   Ruirui Yun,b   Yanpeng Fan,a   Mingsheng Ding,a   Xiaolian Hua  and  Pinggui Yi*a  

* Corresponding authors

a Key Laboratory of Theoretical Organic Chemistry and Function Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
E-mail: zbaishu@163.com, hnust_chem@163.com, yipinggui@sohu.com

b College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, China

Abstract

A microporous acylamide-functionalized MOF with a 2-fold interpenetrated and methyl decorated framework (HNUST-4) has been designed and synthesized from [Cu2(COO)4] motifs and a C2-symmetric acylamide-linking tetracarboxylate, which exhibits good water stability, permanent porosity as well as high and selective CO2 uptake at ambient temperature.

Graphical abstract: Enhanced water stability of a microporous acylamide-functionalized metal–organic framework via interpenetration and methyl decoration

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Article information

DOI
https://doi.org/10.1039/C4CE01165A
Article type
Communication
Submitted
08 Jun 2014
Accepted
06 Aug 2014
First published
07 Aug 2014

CrystEngComm, 2014,16, 9586-9589

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Enhanced water stability of a microporous acylamide-functionalized metal–organic framework via interpenetration and methyl decoration

B. Zheng, X. Lin, Z. Wang, R. Yun, Y. Fan, M. Ding, X. Hu and P. Yi, CrystEngComm, 2014, 16, 9586 DOI: 10.1039/C4CE01165A

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