Issue 97, 2014
From the journal:

Chemical Communications

Exploitation of the majority rules effect for the accurate measurement of high enantiomeric excess values using CD spectroscopy†

Helen M. Seifert,a   Yun-Bao Jiangb  and  Eric V. Anslyn*a  

* Corresponding authors

a Department of Chemistry, University of Texas at Austin, Austin, Texas 78712, USA

b Department of Chemistry, Xiamen University, Xiamen 361005, China
E-mail: anslyn@austin.utexas.edu

Abstract

A new method for lowering the error of CD based methods for measuring high enantiomeric excess values is described, which exploits the majority rules effect exhibited by certain helical polymers. A proof of principle experiment was conducted.

Graphical abstract: Exploitation of the majority rules effect for the accurate measurement of high enantiomeric excess values using CD spectroscopy

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Article information

DOI
https://doi.org/10.1039/C4CC07927B
Article type
Communication
Submitted
07 Oct 2014
Accepted
08 Oct 2014
First published
21 Oct 2014

Chem. Commun., 2014,50, 15330-15332

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Exploitation of the majority rules effect for the accurate measurement of high enantiomeric excess values using CD spectroscopy

H. M. Seifert, Y. Jiang and E. V. Anslyn, Chem. Commun., 2014, 50, 15330 DOI: 10.1039/C4CC07927B

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