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Issue 77, 2014
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A photoinduced mixed-valence state in an organic bis-triarylamine mixed-valence compound with an iridium-metal-bridge

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Abstract

Upon irradiation a mixed-valence (MV) state is formed in a donor–iridium(III)–acceptor triad by a photoinduced electron transfer process. The resulting radical and intervalence charge transfer (IV-CT) absorptions cover a wide spectral range (3200–400 nm). These results were supported by spectroelectrochemistry, fs-time resolved pump–probe spectroscopy and assisted by TD-DFT calculations.

Graphical abstract: A photoinduced mixed-valence state in an organic bis-triarylamine mixed-valence compound with an iridium-metal-bridge

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Publication details

The article was received on 26 Jun 2014, accepted on 31 Jul 2014 and first published on 01 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC04885G
Chem. Commun., 2014,50, 11350-11353

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    A photoinduced mixed-valence state in an organic bis-triarylamine mixed-valence compound with an iridium-metal-bridge

    C. Lambert, R. Wagener, J. H. Klein, G. Grelaud, M. Moos, A. Schmiedel, M. Holzapfel and T. Bruhn, Chem. Commun., 2014, 50, 11350
    DOI: 10.1039/C4CC04885G

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