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Issue 77, 2014
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The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions

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Abstract

Density functional theory (DFT) calculations were carried out to investigate the [2+2], [3+2] and [4+2] cycloadditions of the phosphaethynolate anion (PCO). The results reveal that the electronic properties of different unsaturated compounds play a crucial role in reactivity and regioselectivity.

Graphical abstract: The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions

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Publication details

The article was received on 17 Jun 2014, accepted on 30 Jul 2014 and first published on 01 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC04610B
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Chem. Commun., 2014,50, 11347-11349
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    The phosphaethynolate anion reacts with unsaturated bonds: DFT investigations into [2+2], [3+2] and [4+2] cycloadditions

    L. Liu, J. Zhu and Y. Zhao, Chem. Commun., 2014, 50, 11347
    DOI: 10.1039/C4CC04610B

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